Kane jumps to mind too, both when he won the ECW Championship and then the World Heavyweight Championship. He beat Chavo in something like 8 seconds @ WM 24 for the ECW belt, and then he wins the SD! Money in the Bank contract at Money in the Bank 2010, and cashed in later the same night, defeating Rey in what I believe made him the first superstar to win and cash in the contract successfully on the same night IIRC.
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